CLEARTRAN®
Water-clear Form of Zinc Sulfide

CLEARTRAN®, with its low absorption and scatter throughout its broad transmitting range, is particularly well-suited for multi-spectral applications that require a single aperture or beam path for several wavebands. For example, CLEARTRAN® can be used in systems that have a visible camera, a mid- and long-wave detector and a laser rangefinder or target designator. Additionally, CLEARTRAN® has been supplied as external windows for military systems, and as thick apertures for specialized sensor applications.

Summary:

Description
Advanced Materials' CLEARTRAN® (water clear zinc sulfide) is a form of CVD ZINC SULFIDE® that is modified by a post-deposition hot isostatic press. This process removes zinc hydrides from the crystal lattice, normalizes crystal structure and purifies the material, all contributing to single crystal like transmittance in the visible through far infrared regions (0.4-14 microns).

CLEARTRAN® is chemically inert, non-hygroscopic, highly pure, theoretically dense, and easily machined.

Available Forms
Custom diameters, rectangles, CNC-profiled blanks, generated lens blanks, prisms and near-net shape domes can also be made to your specifications. Sheet material is also available.

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Transmission

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Optical Properties:
10% transmission limits (t=6mm) 0.37 - 14µm
Stress Birefringence < 40nm/cm
Forward Scatter (@ 0.6328µm) < 7 % cm-1
Index of refraction inhomogeneity (Dn/n)
  (ppm @ 0.6328µm) <20
Thermo-optic coefficient, dn/dT(298-358K)
  (1/K @ 0.6328µm) 5.43 x 10-5
(1/K @ 1.15µm) 4.21 x 10-5
(1/K @ 3.39µm) 3.87 x 10-5
Bulk absorption coefficient
  (1/cm @ 1.3µm) 6.0 x 10-4
(1/cm @ 2.7µm) 1.0 x 10-3
(1/cm @ 3.8µm) 6.0 x 10-4
(1/cm @ 9.27µm) 6.0 x 10-3
(1/cm @ 10.6µm) 2.0 x 10-1

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Indices of Refraction (n)
as a function of wavelength at room temperature (20°C)
Wavelength (µ) n Wavelength (µ) n
0.4047 2.54515 1.1287 2.28485
0.4358 2.48918 1.5296 2.27191
0.4678 2.44915 2.0581 2.26442
0.4800 2.43691 3.000 2.25772
0.5086 2.41279 3.500 2.25498
0.5461 2.38838 4.000 2.25231
0.5876 2.36789 4.500 2.24955
0.6438 2.34731 5.000 2.24661
0.6678 2.34033 8.000 2.22334
0.7065 2.33073 9.000 2.21290
0.7800 2.31669 10.000 2.20084
0.7948 2.31438 11.250 2.18317
0.8521 2.30659 12.000 2.17101
0.8943 2.30183 13.000 2.15252
1.0140 2.29165    

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Physical Properites:
Crystal structure cubic
Grain size diameter 20 - 35µm
Density (g cm-3@298K) 4.09
Resistivity (-cm) ~1013
Chemical Purity (%) 99.9996
Dielectric constant data is available from Rohm and Haas.

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Thermal Properties:
Coefficient of Thermal Expansion
  (1/K @ 273 K) 6.3 x 10-6
(1/K @ 373 K) 7.0 x 10-6
(1/K @ 473 K) 7.5 x 10-6
(1/K @ 208 - 573K) 6.5 x 10-6
Thermal conductivity
- (J/K-m-s @ 298 K) 27.2
Heat Capacity (J/g-K @ 273 K) 0.515
  (J/g-K @ 323 K) 0.527
(J/g-K @ 373 K) 0.527
Thermal Diffusivity m2/s 1.3 x 10-5
Maximum operating temperature will depend on the environment

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Mechanical Properties:
Hardness: Knoop, 50 gm load (kg mm-2) 160
  Vickers, 1 kg load (kg mm-2) 150
Flexural Strength (modulus of rupture)
  4 pt. loading (psi) 10 x 103
4 pt. loading (MPa) 60
Disc. Bursting (MPa) 50
Fracture toughness (critical stress intensity factor, KIC values)
  (MPa, Vickers, 1 Kg) 1.0
Young's Modulus (elastic modulus)
  (psi) 10.8 x 106
(GPa) 74.5
Poisson's ratio 0.28
Rain erosion resistance will depend on the environment

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